{
  "schema": 1,
  "slug": "przechowywanie-kwasow-i-zasad",
  "snapshot": "2026-10-15",
  "generatedAt": "2026-10-15T03:42:40.263Z",
  "title": "Kwasy i zasady z tabeli odporności: klasyfikacja CLP a wspólne przechowywanie",
  "method": "Lista zamknięta: z eksportu publicznego zbioru chemical-resistance 2026-09-24 (sha256 sprawdzony z jego deskryptorem) wybrano odczynniki z \"acid\" w identyfikatorze albo nazwie angielskiej (kwasy) oraz z \"hydroxide\" albo \"ammonia\" w identyfikatorze (zasady), ze stężeniem z bazy. Klasyfikację zharmonizowaną pobrano adapterem chem z PubChem (wpisy Załącznika VI CLP pasujące do związku), bez zgłoszeń ECHA. Wpis dla odczynnika wybiera reguła: roztwór odrzuca wpisy gazu i postaci bezwodnej, warunek stężenia w nazwie wpisu musi być spełniony, przy kilku wpisach wygrywa jedyny wpis roztworu, w innym wypadku brak wyboru. Grupy zagrożeń według piktogramu wpisu: GHS03 utleniające, GHS05 żrące, GHS06 trujące, GHS02 łatwopalne, GHS08 zagrożenie dla zdrowia. Liczebności z mianownikiem listy, bez udziałów i przedziałów.",
  "tooling": {
    "node": "v26.11.1",
    "gitSha": "06be5f62f84ed2e63e38754aec7a4e246b4042c1",
    "gitDirty": true,
    "codeSha256": "75b7461b82440a0184ed8ec9e8c2ead55f4f98d915b9d773b42832a4a999ea2d",
    "ua": "RenggliResearchBot/1.0 (+https://www.renggli.pl; mailto:biuro@renggli.pl) node/26.11.1"
  },
  "files": [
    {
      "name": "reagents.csv",
      "rows": 17,
      "bytes": 1450,
      "sha256": "7e25927e8330127696b6e6ccc7b88a2d4fcaada643cf279b61fc0f5d20b4f4aa"
    },
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      "name": "clp_entries.csv",
      "rows": 8,
      "bytes": 1512,
      "sha256": "abf0d93d443260503bf604530bc2dcc01b18a393731e8a25fde75bd748639e56"
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      "bytes": 5859,
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  "sample": {
    "n": 17,
    "unit": "kwasy i zasady z listy 80 odczynników tabeli odporności (pełna lista)",
    "acids": 13,
    "bases": 4,
    "queries": 10,
    "clpEntries": 8
  },
  "verification": {
    "status": "lista zamknięta kwasów i zasad z eksportu publicznego zbioru chemical-resistance 2026-09-24; wpis Załącznika VI CLP wybrany dla stężenia odczynnika: 11 z 17; progi stężeń (SCL) wpisów nie są w danych",
    "note": "Klasyfikacja zharmonizowana odczytana przez PubChem (miejsce odczytu, nie tekst skonsolidowany Załącznika VI); przy wpisach z Uwagą B część zwrotów obowiązuje dopiero od progu stężenia, którego dane nie mają, więc grupa zagrożeń opisuje wpis substancji, nie roztwór o stężeniu z tabeli.",
    "state": "closed-list-clp-via-pubchem"
  },
  "headline": {
    "withEntry": {
      "k": 11,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "citric-acid-10",
        "hydrofluoric-acid-48",
        "acetic-acid-5",
        "acetic-acid-glacial",
        "sulfuric-acid-33",
        "sulfuric-acid-60",
        "sulfuric-acid-96",
        "sodium-hydroxide-10",
        "sodium-hydroxide-50"
      ]
    },
    "noEntry": {
      "k": 6,
      "n": 17,
      "closedList": true,
      "reagents": [
        "ammonia-solution-25",
        "chromic-sulfuric-acid",
        "chromic-acid-40",
        "phosphoric-acid-85",
        "oleic-acid",
        "ammonium-hydroxide-28"
      ]
    },
    "oxidizing": {
      "pictogram": "GHS03",
      "k": 2,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65"
      ],
      "acids": 2,
      "bases": 0,
      "concentrationOpen": [
        "nitric-acid-10",
        "nitric-acid-approx-65"
      ]
    },
    "corrosive": {
      "pictogram": "GHS05",
      "k": 10,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "hydrofluoric-acid-48",
        "acetic-acid-5",
        "acetic-acid-glacial",
        "sulfuric-acid-33",
        "sulfuric-acid-60",
        "sulfuric-acid-96",
        "sodium-hydroxide-10",
        "sodium-hydroxide-50"
      ],
      "acids": 8,
      "bases": 2,
      "concentrationOpen": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "hydrofluoric-acid-48",
        "acetic-acid-5",
        "acetic-acid-glacial",
        "sulfuric-acid-33",
        "sulfuric-acid-60",
        "sulfuric-acid-96"
      ]
    },
    "toxic": {
      "pictogram": "GHS06",
      "k": 3,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "hydrofluoric-acid-48"
      ],
      "acids": 3,
      "bases": 0,
      "concentrationOpen": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "hydrofluoric-acid-48"
      ]
    },
    "flammable": {
      "pictogram": "GHS02",
      "k": 2,
      "n": 17,
      "closedList": true,
      "reagents": [
        "acetic-acid-5",
        "acetic-acid-glacial"
      ],
      "acids": 2,
      "bases": 0,
      "concentrationOpen": [
        "acetic-acid-5",
        "acetic-acid-glacial"
      ]
    },
    "healthHazard": {
      "pictogram": "GHS08",
      "k": 0,
      "n": 17,
      "closedList": true,
      "reagents": [],
      "acids": 0,
      "bases": 0,
      "concentrationOpen": []
    },
    "corrosiveAndOxidizing": {
      "k": 2,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65"
      ]
    },
    "corrosiveAndToxic": {
      "k": 3,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "hydrofluoric-acid-48"
      ]
    },
    "concentrationOpen": {
      "k": 8,
      "n": 17,
      "closedList": true,
      "reagents": [
        "nitric-acid-10",
        "nitric-acid-approx-65",
        "hydrofluoric-acid-48",
        "acetic-acid-5",
        "acetic-acid-glacial",
        "sulfuric-acid-33",
        "sulfuric-acid-60",
        "sulfuric-acid-96"
      ]
    }
  },
  "tables": {
    "acidsBases": {
      "caption": "pełna lista: kwasy i zasady z listy 80 odczynników tabeli odporności, wpis Załącznika VI CLP wybrany dla stężenia",
      "closedList": true,
      "n": 17,
      "rows": [
        {
          "reagent": "ammonia-solution-25",
          "namePl": "Amoniak 25%",
          "kind": "zasada",
          "concentration": "25%",
          "query": "ammonium hydroxide",
          "clpIndex": "",
          "entryName": "",
          "entryForm": "",
          "signal": "",
          "hazards": [],
          "pictograms": [],
          "groups": [],
          "selection": "brak wpisu Załącznika VI pasującego do związku w PubChem",
          "candidateStatus": "no-data",
          "candidateFlags": [
            "echa-only"
          ],
          "openFlags": [
            "no-entry"
          ],
          "url": ""
        },
        {
          "reagent": "chromic-sulfuric-acid",
          "namePl": "Chromianka (mieszanina chromowa)",
          "kind": "kwas",
          "concentration": "",
          "query": "",
          "clpIndex": "",
          "entryName": "",
          "entryForm": "",
          "signal": "",
          "hazards": [],
          "pictograms": [],
          "groups": [],
          "selection": "mieszanina bez jednego związku: brak zapytania i wpisu Załącznika VI",
          "candidateStatus": "",
          "candidateFlags": [],
          "openFlags": [],
          "url": ""
        },
        {
          "reagent": "nitric-acid-10",
          "namePl": "Kwas azotowy 10%",
          "kind": "kwas",
          "concentration": "10%",
          "query": "nitric acid",
          "clpIndex": "007-030-00-3",
          "entryName": "nitric acid …% [C ≤ 70 %]",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H272",
            "H314",
            "H331"
          ],
          "pictograms": [
            "GHS03",
            "GHS05",
            "GHS06"
          ],
          "groups": [
            "oxidizing",
            "corrosive",
            "toxic"
          ],
          "selection": "warunek stężenia w nazwie wpisu wyklucza 1 wpis(y)",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-dependent"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/944#section=GHS-Classification"
        },
        {
          "reagent": "nitric-acid-approx-65",
          "namePl": "Kwas azotowy ok. 65%",
          "kind": "kwas",
          "concentration": "ok. 65%",
          "query": "nitric acid",
          "clpIndex": "007-030-00-3",
          "entryName": "nitric acid …% [C ≤ 70 %]",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H272",
            "H314",
            "H331"
          ],
          "pictograms": [
            "GHS03",
            "GHS05",
            "GHS06"
          ],
          "groups": [
            "oxidizing",
            "corrosive",
            "toxic"
          ],
          "selection": "warunek stężenia w nazwie wpisu wyklucza 1 wpis(y)",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-dependent"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/944#section=GHS-Classification"
        },
        {
          "reagent": "chromic-acid-40",
          "namePl": "Kwas chromowy 40%",
          "kind": "kwas",
          "concentration": "40%",
          "query": "chromic acid",
          "clpIndex": "",
          "entryName": "",
          "entryForm": "",
          "signal": "",
          "hazards": [],
          "pictograms": [],
          "groups": [],
          "selection": "brak wpisu Załącznika VI pasującego do związku w PubChem",
          "candidateStatus": "no-data",
          "candidateFlags": [
            "echa-only"
          ],
          "openFlags": [
            "no-entry"
          ],
          "url": ""
        },
        {
          "reagent": "citric-acid-10",
          "namePl": "Kwas cytrynowy 10%",
          "kind": "kwas",
          "concentration": "10%",
          "query": "citric acid",
          "clpIndex": "607-750-00-3",
          "entryName": "citric acid",
          "entryForm": "",
          "signal": "Warning",
          "hazards": [
            "H319",
            "H335"
          ],
          "pictograms": [
            "GHS07"
          ],
          "groups": [],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "candidate",
          "candidateFlags": [],
          "openFlags": [],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/311#section=GHS-Classification"
        },
        {
          "reagent": "hydrofluoric-acid-48",
          "namePl": "Kwas fluorowodorowy 48%",
          "kind": "kwas",
          "concentration": "48%",
          "query": "hydrofluoric acid",
          "clpIndex": "009-003-00-1",
          "entryName": "hydrofluoric acid ... %",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H300",
            "H310",
            "H314",
            "H330"
          ],
          "pictograms": [
            "GHS05",
            "GHS06"
          ],
          "groups": [
            "corrosive",
            "toxic"
          ],
          "selection": "wybrano jedyny wpis roztworu",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-dependent",
            "flash-point-not-open"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/14917#section=GHS-Classification"
        },
        {
          "reagent": "phosphoric-acid-85",
          "namePl": "Kwas fosforowy 85%",
          "kind": "kwas",
          "concentration": "85%",
          "query": "phosphoric acid",
          "clpIndex": "",
          "entryName": "",
          "entryForm": "",
          "signal": "",
          "hazards": [],
          "pictograms": [],
          "groups": [],
          "selection": "brak wpisu Załącznika VI pasującego do związku w PubChem",
          "candidateStatus": "no-data",
          "candidateFlags": [
            "echa-only"
          ],
          "openFlags": [
            "no-entry"
          ],
          "url": ""
        },
        {
          "reagent": "acetic-acid-5",
          "namePl": "Kwas octowy 5%",
          "kind": "kwas",
          "concentration": "5%",
          "query": "acetic acid",
          "clpIndex": "607-002-00-6",
          "entryName": "acetic acid … %",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H226",
            "H314"
          ],
          "pictograms": [
            "GHS02",
            "GHS05"
          ],
          "groups": [
            "corrosive",
            "flammable"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-limits"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/176#section=GHS-Classification"
        },
        {
          "reagent": "acetic-acid-glacial",
          "namePl": "Kwas octowy lodowaty",
          "kind": "kwas",
          "concentration": "",
          "query": "acetic acid",
          "clpIndex": "607-002-00-6",
          "entryName": "acetic acid … %",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H226",
            "H314"
          ],
          "pictograms": [
            "GHS02",
            "GHS05"
          ],
          "groups": [
            "corrosive",
            "flammable"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-limits"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/176#section=GHS-Classification"
        },
        {
          "reagent": "oleic-acid",
          "namePl": "Kwas oleinowy",
          "kind": "kwas",
          "concentration": "",
          "query": "oleic acid",
          "clpIndex": "",
          "entryName": "",
          "entryForm": "",
          "signal": "",
          "hazards": [],
          "pictograms": [],
          "groups": [],
          "selection": "brak wpisu Załącznika VI pasującego do związku w PubChem",
          "candidateStatus": "candidate",
          "candidateFlags": [
            "echa-only"
          ],
          "openFlags": [
            "no-entry"
          ],
          "url": ""
        },
        {
          "reagent": "sulfuric-acid-33",
          "namePl": "Kwas siarkowy 33%",
          "kind": "kwas",
          "concentration": "33%",
          "query": "sulfuric acid",
          "clpIndex": "016-020-00-8",
          "entryName": "sulphuric acid ... %",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H314"
          ],
          "pictograms": [
            "GHS05"
          ],
          "groups": [
            "corrosive"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-limits"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/1118#section=GHS-Classification"
        },
        {
          "reagent": "sulfuric-acid-60",
          "namePl": "Kwas siarkowy 60%",
          "kind": "kwas",
          "concentration": "60%",
          "query": "sulfuric acid",
          "clpIndex": "016-020-00-8",
          "entryName": "sulphuric acid ... %",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H314"
          ],
          "pictograms": [
            "GHS05"
          ],
          "groups": [
            "corrosive"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-limits"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/1118#section=GHS-Classification"
        },
        {
          "reagent": "sulfuric-acid-96",
          "namePl": "Kwas siarkowy 96%",
          "kind": "kwas",
          "concentration": "96%",
          "query": "sulfuric acid",
          "clpIndex": "016-020-00-8",
          "entryName": "sulphuric acid ... %",
          "entryForm": "roztwór (stężenie w nazwie wpisu)",
          "signal": "Danger",
          "hazards": [
            "H314"
          ],
          "pictograms": [
            "GHS05"
          ],
          "groups": [
            "corrosive"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "needs-review",
          "candidateFlags": [
            "concentration-limits"
          ],
          "openFlags": [
            "concentration-limits"
          ],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/1118#section=GHS-Classification"
        },
        {
          "reagent": "ammonium-hydroxide-28",
          "namePl": "Wodorotlenek amonu 28%",
          "kind": "zasada",
          "concentration": "28%",
          "query": "ammonium hydroxide",
          "clpIndex": "",
          "entryName": "",
          "entryForm": "",
          "signal": "",
          "hazards": [],
          "pictograms": [],
          "groups": [],
          "selection": "brak wpisu Załącznika VI pasującego do związku w PubChem",
          "candidateStatus": "no-data",
          "candidateFlags": [
            "echa-only"
          ],
          "openFlags": [
            "no-entry"
          ],
          "url": ""
        },
        {
          "reagent": "sodium-hydroxide-10",
          "namePl": "Wodorotlenek sodu 10%",
          "kind": "zasada",
          "concentration": "10%",
          "query": "sodium hydroxide",
          "clpIndex": "011-002-00-6",
          "entryName": "sodium hydroxide; caustic soda",
          "entryForm": "",
          "signal": "Danger",
          "hazards": [
            "H314"
          ],
          "pictograms": [
            "GHS05"
          ],
          "groups": [
            "corrosive"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "candidate",
          "candidateFlags": [],
          "openFlags": [],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/14798#section=GHS-Classification"
        },
        {
          "reagent": "sodium-hydroxide-50",
          "namePl": "Wodorotlenek sodu 50%",
          "kind": "zasada",
          "concentration": "50%",
          "query": "sodium hydroxide",
          "clpIndex": "011-002-00-6",
          "entryName": "sodium hydroxide; caustic soda",
          "entryForm": "",
          "signal": "Danger",
          "hazards": [
            "H314"
          ],
          "pictograms": [
            "GHS05"
          ],
          "groups": [
            "corrosive"
          ],
          "selection": "jedyny pasujący wpis",
          "candidateStatus": "candidate",
          "candidateFlags": [],
          "openFlags": [],
          "url": "https://pubchem.ncbi.nlm.nih.gov/compound/14798#section=GHS-Classification"
        }
      ]
    }
  },
  "disputed": []
}